This paper deals with characteristics analysis of surface-mounted PM (SPM) motor for compressor of air-conditioning system for Electric Vehicle according to slot/pole combinations. Restricted conditions such as motor size limit and current density are also determined. And then, under same rated and restricted conditions, twelve models which have different slot/pole combinations each other are designed for various pole arc/pitch ratio using simple equations and 2-d finite element (FE) analyses. Designed models are analyzed and compared in terms of back-emf THD, cogging torque, torque ripple, power losses, efficiency, etc. On the basis of analysis results, it is found that the motor with a 6-pole PM rotor and a 27-slot stator has most outstanding performances in electromagnetic aspects.